Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations.
نویسندگان
چکیده
Ketones are efficiently deoxygenated in the presence of silane using highly electrophilic phosphonium cation (EPC) salts as catalysts, thus affording the corresponding alkane and siloxane. The influence of distinct substitution patterns on the catalytic effectiveness of several EPCs was evaluated. The deoxygenation mechanism was probed by DFT methods.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 54 28 شماره
صفحات -
تاریخ انتشار 2015